diff --git a/Headers/CMN_FJX_MOD.F90 b/Headers/CMN_FJX_MOD.F90 index f5bcffe6c..940fc296c 100644 --- a/Headers/CMN_FJX_MOD.F90 +++ b/Headers/CMN_FJX_MOD.F90 @@ -31,7 +31,7 @@ MODULE CMN_FJX_MOD ! Parameters !----------------------------------------------------------------------- - INTEGER, PARAMETER :: JVN_ = 166 ! Max number of J-values + INTEGER, PARAMETER :: JVN_ = 167 ! Max number of J-values INTEGER, PARAMETER :: WX_ = 18 ! # wavelengths in file FJX_spec.dat diff --git a/KPP/custom/custom.eqn b/KPP/custom/custom.eqn index 890e15c53..22afe6daf 100644 --- a/KPP/custom/custom.eqn +++ b/KPP/custom/custom.eqn @@ -511,6 +511,7 @@ ALD2 + OH = 0.950MCO3 + 0.050CH2O + ALD2 + NO3 = HNO3 + MCO3 : GCARR_ac(1.40d-12, -1900.0d0); MCO3 + NO2 {+M} = PAN : GCJPLPR_abab(7.30d-29, 4.1d+00, 9.5d-12, 1.6d0, 0.6d0); {2023/04/18; JPL 19-5; KHB} PAN = MCO3 + NO2 : GCJPLEQ_acabab(9.00d-29, 14000.0d0, 7.3d-29, 4.1d0, 9.5d-12, 1.6d0, 0.6d0); {2023/04/18; JPL 19-5; KHB} +PAN + OH = CH2O + CO + NO2 : 3.00d-14 ; MCO3 + NO = MO2 + NO2 + CO2 : GCARR_ac(8.10d-12, 270.0d0); C2H6 + OH = ETO2 + H2O : GCARR_ac(7.66d-12, -1020.0d0); {2013/02/12; JPL 10-6; BHH,JMAO,EAM} ETO2 + NO = ALD2 + NO2 + HO2 : GC_RO2NO_B2_aca(2.60d-12, 365.0d0, 2.0d0); {2019/05/10; Fisher2018; JAF} @@ -541,6 +542,7 @@ ACTA + OH = MO2 + CO2 + H2O : GCARR_ac(3.15d-14, 920.0d0); OH + RCHO = RCO3 + H2O : GCARR_ac(6.00d-12, 410.0d0); RCO3 + NO2 {+M} = PPN : GCJPLPR_abab(9.00d-28, 8.9d0, 7.7d-12, 0.2d0, 0.6d0); {JPL Eval 17} PPN = RCO3 + NO2 : GCJPLEQ_acabab(9.00d-29, 14000.0d0, 9.00d-28, 8.9d0, 7.7d-12, 0.2d0, 0.6d0); +PPN + OH = ALD2 + CO + NO2 : 1.27d-12 ; RCO3 + NO = NO2 + 0.490OTHRO2 + 0.070A3O2 + 0.270B3O2 + CO2 : GCARR_ac(6.70d-12, 340.0d0); {2019/05/10; Fisher2018; JAF; 2023/04/18; Bates2023; KHB} RCHO + NO3 = HNO3 + RCO3 : 6.50d-15; @@ -1547,6 +1549,8 @@ ALD2 + hv = 0.880MO2 + HO2 + 0.880CO + ALD2 + hv = CH4 + CO : PHOTOL(62); PAN + hv = 0.700MCO3 + 0.700NO2 + 0.300MO2 + 0.300NO3 + 0.300CO2 : PHOTOL(59); {2014/05/23; Eastham2014; JMAO,SDE; 2023/04/18; Bates2023; KHB} +PPN + hv = 0.700RCO3 + 0.700NO2 + + 0.300NO3 : PHOTOL(167); {2024/07/11; Horner2024} RCHO + hv = 0.490OTHRO2 + HO2 + CO + 0.070A3O2 + 0.270B3O2 : PHOTOL(70); {2019/05/10; Fisher2018; JAF; 2023/04/18; Bates2023; KHB} ACET + hv = MCO3 + MO2 : PHOTOL(76); diff --git a/KPP/fullchem/CHANGELOG_fullchem.md b/KPP/fullchem/CHANGELOG_fullchem.md index 50eba3202..1719f5206 100644 --- a/KPP/fullchem/CHANGELOG_fullchem.md +++ b/KPP/fullchem/CHANGELOG_fullchem.md @@ -119,3 +119,9 @@ The format is based on [Keep a Changelog](https://keepachangelog.com/en/1.0.0/), ## [v11-01g] - Sep 2016 ### Added - Initial version for FlexChem (MSL,MJE,MPS,EWL) + +## [v14.4.1] - July 2024 +### Added +- Photolysis of PPN from Horner2024 (BH) +- PPN+OH and PAN+OH based on the structure activity relationship approach (BH) + diff --git a/KPP/fullchem/fullchem.eqn b/KPP/fullchem/fullchem.eqn index 9d7ea2b2e..b53981795 100644 --- a/KPP/fullchem/fullchem.eqn +++ b/KPP/fullchem/fullchem.eqn @@ -509,6 +509,7 @@ ALD2 + OH = 0.950MCO3 + 0.050CH2O + ALD2 + NO3 = HNO3 + MCO3 : GCARR_ac(1.40d-12, -1900.0d0); MCO3 + NO2 {+M} = PAN : GCJPLPR_abab(7.30d-29, 4.1d+00, 9.5d-12, 1.6d0, 0.6d0); {2023/04/18; JPL 19-5; KHB} PAN = MCO3 + NO2 : GCJPLEQ_acabab(9.00d-29, 14000.0d0, 7.3d-29, 4.1d0, 9.5d-12, 1.6d0, 0.6d0); {2023/04/18; JPL 19-5; KHB} +PAN + OH = CH2O + CO + NO2 : 3.00d-14 ; MCO3 + NO = MO2 + NO2 + CO2 : GCARR_ac(8.10d-12, 270.0d0); C2H6 + OH = ETO2 + H2O : GCARR_ac(7.66d-12, -1020.0d0); {2013/02/12; JPL 10-6; BHH,JMAO,EAM} ETO2 + NO = ALD2 + NO2 + HO2 : GC_RO2NO_B2_aca(2.60d-12, 365.0d0, 2.0d0); {2019/05/10; Fisher2018; JAF} @@ -539,6 +540,7 @@ ACTA + OH = MO2 + CO2 + H2O : GCARR_ac(3.15d-14, 920.0d0); OH + RCHO = RCO3 + H2O : GCARR_ac(6.00d-12, 410.0d0); RCO3 + NO2 {+M} = PPN : GCJPLPR_abab(9.00d-28, 8.9d0, 7.7d-12, 0.2d0, 0.6d0); {JPL Eval 17} PPN = RCO3 + NO2 : GCJPLEQ_acabab(9.00d-29, 14000.0d0, 9.00d-28, 8.9d0, 7.7d-12, 0.2d0, 0.6d0); +PPN + OH = ALD2 + CO + NO2 : 1.27d-12 ; RCO3 + NO = NO2 + 0.490OTHRO2 + 0.070A3O2 + 0.270B3O2 + CO2 : GCARR_ac(6.70d-12, 340.0d0); {2019/05/10; Fisher2018; JAF; 2023/04/18; Bates2023; KHB} RCHO + NO3 = HNO3 + RCO3 : 6.50d-15; @@ -1545,6 +1547,8 @@ ALD2 + hv = 0.880MO2 + HO2 + 0.880CO + ALD2 + hv = CH4 + CO : PHOTOL(62); PAN + hv = 0.700MCO3 + 0.700NO2 + 0.300MO2 + 0.300NO3 + 0.300CO2 : PHOTOL(59); {2014/05/23; Eastham2014; JMAO,SDE; 2023/04/18; Bates2023; KHB} +PPN + hv = 0.700RCO3 + 0.700NO2 + + 0.300NO3 : PHOTOL(167); {2024/07/11; Horner2024} RCHO + hv = 0.490OTHRO2 + HO2 + CO + 0.070A3O2 + 0.270B3O2 : PHOTOL(70); {2019/05/10; Fisher2018; JAF; 2023/04/18; Bates2023; KHB} ACET + hv = MCO3 + MO2 : PHOTOL(76);