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bridge derivation: classical particles and quantum superposition #26

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bhpayne opened this issue Jan 29, 2025 · 2 comments
Open

bridge derivation: classical particles and quantum superposition #26

bhpayne opened this issue Jan 29, 2025 · 2 comments
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@bhpayne
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bhpayne commented Jan 29, 2025

bridging the assumptions that distinguish classical particles from quantum concept of superposition

@bhpayne
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bhpayne commented Jan 29, 2025

prompt

In classical mechanics a particle has a single, definite value for properties like position, momentum, and spin at any given time.

In quantum mechanics, particles can exist in a superposition of multiple states simultaneously until a measurement is made. For example, an electron can be in a superposition of spin-up and spin-down states.

In mathematical Physics a derivation is comprised of steps and equations. Is there a derivation that bridges the classical view of particles with the quantum concept of superposition? If yes, provide the steps of the derivation. Format the answer using Latex as a single file.

Latex is a software system for typesetting documents. LaTeX is widely used for the communication and publication of scientific documents and technical note-taking in many fields, owing partially to its support for complex mathematical notation.

Do not have equations inline with the text. Equations should be separate and inside a math environment for Latex:

\begin{equation}
\end{equation}

Each equation should have a left-hand side and right-hand side. Specify mathematical equations explicitly. Define the variables used in equations.

thoughts

The user is asking for a derivation that bridges classical mechanics and quantum mechanics regarding the concept of superposition.
This is a very complex question, as classical mechanics and quantum mechanics are fundamentally different frameworks. Classical mechanics is deterministic, while quantum mechanics is probabilistic and allows for superposition.

It's unlikely there is a single, simple derivation that directly bridges these two concepts in a way that shows superposition naturally emerging from classical mechanics. Quantum mechanics doesn't "emerge" from classical mechanics; it's a different, more fundamental description of nature.

However, we can consider how the need for quantum mechanics and superposition arises when classical mechanics fails. We can highlight situations where classical mechanics breaks down and quantum mechanics is needed to explain observations, leading to the concept of superposition.

Thinking about the historical development might be helpful. Quantum mechanics wasn't derived from classical mechanics. It was developed to explain phenomena that classical mechanics couldn't, like blackbody radiation, the photoelectric effect, and atomic spectra. These phenomena suggested quantization and wave-particle duality, leading to the development of quantum theory.

Instead of a direct derivation, we can aim to show the motivation for moving from a classical description to a quantum description that includes superposition. This might involve:

  1. Classical Description: Briefly describe how classical mechanics treats particles with definite properties.
  2. Limitations of Classical Mechanics: Point out phenomena classical mechanics cannot explain, focusing on aspects that hint at superposition-like behavior or the breakdown of definite classical properties. Perhaps examples from wave optics and interference could be used as an analogy, even though they are not directly about particles in the classical sense.
  3. Quantum Mechanical Description: Introduce the quantum mechanical concept of superposition as a necessary framework to describe the observed phenomena.
  4. Analogy (Optional): Maybe use an analogy to illustrate superposition, like waves. Although waves are classical, their superposition behavior is conceptually similar to quantum superposition.
  5. No Direct Derivation: Explicitly state that there's no direct derivation from classical mechanics to quantum superposition in the sense of a step-by-step mathematical transformation. Instead, quantum mechanics is a new framework.

Let's refine the approach to be more concrete and closer to what the user might be expecting, even if a literal derivation is not possible:

  • Start with Classical State: Define the classical state of a particle using position and momentum (or spin, if we want to link to the example).
  • Classical Evolution: Describe how classical properties evolve deterministically according to classical equations of motion (Newton's laws or Hamiltonian mechanics).
  • Problem with Classical Description (e.g., Spin): Consider spin, as the user mentioned spin-up and spin-down. Classically, spin is a vector with a definite direction. However, experiments like Stern-Gerlach show quantized spin and outcomes that are not easily explained classically before quantum mechanics.
  • Introduce Quantum State: Introduce the idea of a quantum state using wave functions or state vectors in Hilbert space.
  • Superposition Principle: Postulate the superposition principle as a fundamental aspect of quantum mechanics. Show how linear combinations of quantum states are also valid states.
  • Measurement: Explain how measurement in quantum mechanics collapses the superposition into a definite eigenstate, giving a probabilistic outcome.
  • Contrast with Classical Definiteness: Emphasize the difference: classical mechanics assumes definite values always exist and are revealed by measurement; quantum mechanics states properties can be indefinite (superposed) until measurement.

It's crucial to be clear that we are motivating the introduction of superposition, not deriving it from classical mechanics. The transition is a conceptual and theoretical leap, driven by experimental observations that contradict classical predictions.

Let's structure the Latex response based on this thought process. We will need to define classical states, highlight issues, introduce quantum states and superposition, and emphasize the fundamental difference in description. We will not be able to derive superposition from classical mechanics in the way one derives a mathematical equation from other equations within the same framework. The "derivation" will be more of a logical progression showing why classical mechanics is insufficient and why quantum mechanics with superposition is necessary.

response

\documentclass{article}
\usepackage{amsmath}
\usepackage{amsfonts}

\title{Bridging Classical and Quantum Views: Superposition}
\author{ }
\date{ }

\begin{document}
\maketitle

\section{Classical View of Particles}

In classical mechanics, a particle is described by its definite properties at any given time. These properties include, but are not limited to, position, momentum, and spin.  The state of a classical particle can be fully specified by these properties.

Let's consider a particle's position and momentum in one dimension. In classical mechanics, at any time $t$, a particle has a definite position $x(t)$ and a definite momentum $p(t)$. The state of the particle is represented by a point in phase space $(x, p)$.

The classical state of a particle is definite and evolves deterministically according to classical equations of motion, such as Newton's laws or Hamiltonian equations. For instance, under a potential force $V(x)$, the Hamiltonian $H$ is given by:

\begin{equation}
H(x, p) = \frac{p^2}{2m} + V(x)
\end{equation}
where:
\begin{itemize}
    \item $H$ is the Hamiltonian of the system.
    \item $x$ is the position of the particle.
    \item $p$ is the momentum of the particle.
    \item $m$ is the mass of the particle.
    \item $V(x)$ is the potential energy as a function of position.
\end{itemize}

The time evolution of position and momentum is then given by Hamilton's equations:

\begin{equation}
\dot{x} = \frac{\partial H}{\partial p} = \frac{p}{m}
\end{equation}

\begin{equation}
\dot{p} = -\frac{\partial H}{\partial x} = -\frac{dV(x)}{dx} = F(x)
\end{equation}
where:
\begin{itemize}
    \item $\dot{x} = \frac{dx}{dt}$ is the time derivative of position (velocity).
    \item $\dot{p} = \frac{dp}{dt}$ is the time derivative of momentum (force).
    \item $F(x) = -\frac{dV(x)}{dx}$ is the force acting on the particle.
\end{itemize}

These equations dictate a deterministic evolution of the particle's state. If we know the initial position $x(0)$ and momentum $p(0)$, we can, in principle, determine $x(t)$ and $p(t)$ for all future times $t$.  There is no concept of a particle being in multiple states simultaneously in classical mechanics.

\section{Limitations of Classical Mechanics and the Emergence of Quantum Concepts}

Classical mechanics, while successful in describing macroscopic phenomena, fails to explain many microscopic phenomena observed at the atomic and subatomic levels.  Experiments revealed behaviors that are inconsistent with the classical view of particles having definite properties at all times.

Consider the phenomenon of electron spin.  In classical physics, spin could be thought of as an intrinsic angular momentum vector with a definite direction. However, experiments like the Stern-Gerlach experiment showed that when a beam of silver atoms (with a net spin due to an unpaired electron) passes through an inhomogeneous magnetic field, the beam splits into discrete components, not a continuous spread as would be expected classically. For spin-1/2 particles like electrons, the beam splits into two components, traditionally labeled "spin-up" and "spin-down" along the direction of the magnetic field.

This suggests that the spin component along a particular direction is quantized and can only take on discrete values, unlike a classical continuous vector. Furthermore, if we prepare a beam of spin-up electrons (relative to the z-axis) and then measure their spin along the x-axis, we find that approximately half are measured as spin-up and half as spin-down along the x-axis.  This is not compatible with the classical notion of a definite spin vector that simply has a fixed orientation in space.

To explain these observations, quantum mechanics was developed. A key concept in quantum mechanics is the idea of superposition.

\section{Quantum Mechanical Superposition}

In quantum mechanics, the state of a particle is described by a wave function or a state vector in a Hilbert space. Unlike classical mechanics, physical properties are not always definite until measured. Instead, a quantum system can exist in a superposition of multiple states.

For example, the spin state of an electron can be represented as a vector in a two-dimensional Hilbert space spanned by the basis states $| \uparrow \rangle$ (spin-up) and $| \downarrow \rangle$ (spin-down) along a chosen direction (e.g., z-axis). A general spin state $|\psi \rangle$ can be a linear combination of these basis states:

\begin{equation}
|\psi \rangle = c_1 |\uparrow \rangle + c_2 |\downarrow \rangle
\end{equation}
where:
\begin{itemize}
    \item $|\psi \rangle$ is the quantum state vector representing the spin state of the electron.
    \item $|\uparrow \rangle$ represents the spin-up state along the chosen direction (e.g., z-axis).
    \item $|\downarrow \rangle$ represents the spin-down state along the chosen direction (e.g., z-axis).
    \item $c_1$ and $c_2$ are complex coefficients.
\end{itemize}

The coefficients $c_1$ and $c_2$ are complex numbers, and their squared magnitudes, $|c_1|^2$ and $|c_2|^2$, represent the probabilities of finding the electron in the spin-up state and spin-down state, respectively, when a measurement of spin along the chosen direction is performed.  For a normalized state, we must have:

\begin{equation}
|c_1|^2 + |c_2|^2 = 1
\end{equation}

This superposition principle is a fundamental postulate of quantum mechanics and does not have a direct analog in classical mechanics.  It implies that before a measurement, the electron's spin state is not definitely "up" or "down," but rather exists in a combination of both possibilities.  The act of measurement forces the system to "choose" one of the definite states, with probabilities given by the squared magnitudes of the coefficients in the superposition.

\section{Bridging the Gap: No Direct Derivation, but a Shift in Description}

It is important to understand that there is no direct mathematical derivation that starts from classical mechanics and naturally leads to the concept of quantum superposition. Quantum mechanics is not a derivation or a refinement of classical mechanics; it is a fundamentally different theory that describes nature at a deeper level.

The transition from classical mechanics to quantum mechanics was driven by experimental observations that classical physics could not explain. The concept of superposition was introduced as part of a new theoretical framework that could account for these observations.  It is a postulate of quantum mechanics, supported by vast experimental evidence, rather than a derived result from classical principles.

One can argue that the "derivation" is historical and conceptual.  It is a process of recognizing the limitations of classical mechanics in explaining microscopic phenomena and then constructing a new theory with new postulates, like superposition, that can successfully describe these phenomena.  This is not a derivation in the mathematical sense of manipulating equations, but rather a paradigm shift in how we describe physical reality.

In summary, while we cannot provide a step-by-step mathematical derivation of superposition from classical mechanics, we can highlight the experimental and theoretical necessity for moving from a classical view of definite properties to a quantum view incorporating superposition to accurately describe the behavior of particles at the quantum level. Quantum mechanics, with its principle of superposition, is a more fundamental and comprehensive theory that encompasses classical mechanics as a limiting case for macroscopic systems where quantum effects become negligible.

\end{document}

@bhpayne
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bhpayne commented Jan 29, 2025

prompt

For the following Latex file, write out the file and insert a label for each equation. The label that is added should be descriptive of the equation and contain no spaces, only underscores.

Labels for equations should be unique within the document.

The following Latex file contains a derivation with many steps. Sometimes a previous expression is referenced implicitly. Edit the following text to manually insert references where appropriate. For example replace text like "substitute the forces" with "substitute Eq.~\ref{} to get". Be sure to reference the relevant equation labels so that Latex can compile the document.

Just write the revised Latex file content as your answer.

\documentclass{article}
\usepackage{amsmath}

\title{Bridging Classical and Quantum Views: Superposition}
\author{Ben Payne}
\date{\today}

% margins of 1 inch:
\setlength{\topmargin}{-.5in}
\setlength{\textheight}{9in}
\setlength{\oddsidemargin}{0in}
\setlength{\textwidth}{6.5in}

\usepackage[pdftex]{hyperref} % hyperlink equation and bibliographic citations


\begin{document}
\maketitle

\section{Classical View of Particles}

In classical mechanics, a particle is described by its definite properties at any given time. These properties include, but are not limited to, position, momentum, and spin.  The state of a classical particle can be fully specified by these properties.

Let's consider a particle's position and momentum in one dimension. In classical mechanics, at any time $t$, a particle has a definite position $x(t)$ and a definite momentum $p(t)$. The state of the particle is represented by a point in phase space $(x, p)$.

The classical state of a particle is definite and evolves deterministically according to classical equations of motion, such as Newton's laws or Hamiltonian equations. For instance, under a potential force $V(x)$, the Hamiltonian $H$ is given by:

\begin{equation}
H(x, p) = \frac{p^2}{2m} + V(x)
\end{equation}
where:
\begin{itemize}
    \item $H$ is the Hamiltonian of the system.
    \item $x$ is the position of the particle.
    \item $p$ is the momentum of the particle.
    \item $m$ is the mass of the particle.
    \item $V(x)$ is the potential energy as a function of position.
\end{itemize}

The time evolution of position and momentum is then given by Hamilton's equations:

\begin{equation}
\dot{x} = \frac{\partial H}{\partial p} 
\end{equation}
\begin{equation}
    \dot{x} = \frac{p}{m}
\end{equation}

\begin{equation}
\dot{p} = -\frac{\partial H}{\partial x}
\end{equation}
\begin{equation}
\dot{p} = -\frac{dV(x)}{dx}
\end{equation}
\begin{equation}
\dot{p} = F(x)
\end{equation}
where:
\begin{equation}
\dot{x} = \frac{dx}{dt}    
\end{equation}
 is the time derivative of position (velocity).
\begin{equation}
\dot{p} = \frac{dp}{dt}    
\end{equation}
 is the time derivative of momentum (force).
 \begin{equation}
F(x) = -\frac{dV(x)}{dx}     
 \end{equation}
 is the force acting on the particle.


These equations dictate a deterministic evolution of the particle's state. If we know the initial position $x(0)$ and momentum $p(0)$, we can, in principle, determine $x(t)$ and $p(t)$ for all future times $t$.  There is no concept of a particle being in multiple states simultaneously in classical mechanics.

\section{Limitations of Classical Mechanics and the Emergence of Quantum Concepts}

Classical mechanics, while successful in describing macroscopic phenomena, fails to explain many microscopic phenomena observed at the atomic and subatomic levels.  Experiments revealed behaviors that are inconsistent with the classical view of particles having definite properties at all times.

Consider the phenomenon of electron spin.  In classical physics, spin could be thought of as an intrinsic angular momentum vector with a definite direction. However, experiments like the Stern-Gerlach experiment showed that when a beam of silver atoms (with a net spin due to an unpaired electron) passes through an inhomogeneous magnetic field, the beam splits into discrete components, not a continuous spread as would be expected classically. For spin-1/2 particles like electrons, the beam splits into two components, traditionally labeled "spin-up" and "spin-down" along the direction of the magnetic field.

This suggests that the spin component along a particular direction is quantized and can only take on discrete values, unlike a classical continuous vector. Furthermore, if we prepare a beam of spin-up electrons (relative to the z-axis) and then measure their spin along the x-axis, we find that approximately half are measured as spin-up and half as spin-down along the x-axis.  This is not compatible with the classical notion of a definite spin vector that simply has a fixed orientation in space.

To explain these observations, quantum mechanics was developed. A key concept in quantum mechanics is the idea of superposition.

\section{Quantum Mechanical Superposition}

In quantum mechanics, the state of a particle is described by a wave function or a state vector in a Hilbert space. Unlike classical mechanics, physical properties are not always definite until measured. Instead, a quantum system can exist in a superposition of multiple states.

For example, the spin state of an electron can be represented as a vector in a two-dimensional Hilbert space spanned by the basis states $| \uparrow \rangle$ (spin-up) and $| \downarrow \rangle$ (spin-down) along a chosen direction (e.g., z-axis). A general spin state $|\psi \rangle$ can be a linear combination of these basis states:

\begin{equation}
|\psi \rangle = c_1 |\uparrow \rangle + c_2 |\downarrow \rangle
\end{equation}
where:
\begin{itemize}
    \item $|\psi \rangle$ is the quantum state vector representing the spin state of the electron.
    \item $|\uparrow \rangle$ represents the spin-up state along the chosen direction (e.g., z-axis).
    \item $|\downarrow \rangle$ represents the spin-down state along the chosen direction (e.g., z-axis).
    \item $c_1$ and $c_2$ are complex coefficients.
\end{itemize}

The coefficients $c_1$ and $c_2$ are complex numbers, and their squared magnitudes, $|c_1|^2$ and $|c_2|^2$, represent the probabilities of finding the electron in the spin-up state and spin-down state, respectively, when a measurement of spin along the chosen direction is performed.  For a normalized state, we must have:

\begin{equation}
|c_1|^2 + |c_2|^2 = 1
\end{equation}

This superposition principle is a fundamental postulate of quantum mechanics and does not have a direct analog in classical mechanics.  It implies that before a measurement, the electron's spin state is not definitely "up" or "down," but rather exists in a combination of both possibilities.  The act of measurement forces the system to "choose" one of the definite states, with probabilities given by the squared magnitudes of the coefficients in the superposition.

\section{Bridging the Gap: No Direct Derivation, but a Shift in Description}

It is important to understand that there is no direct mathematical derivation that starts from classical mechanics and naturally leads to the concept of quantum superposition. Quantum mechanics is not a derivation or a refinement of classical mechanics; it is a fundamentally different theory that describes nature at a deeper level.

The transition from classical mechanics to quantum mechanics was driven by experimental observations that classical physics could not explain. The concept of superposition was introduced as part of a new theoretical framework that could account for these observations.  It is a postulate of quantum mechanics, supported by vast experimental evidence, rather than a derived result from classical principles.

One can argue that the "derivation" is historical and conceptual.  It is a process of recognizing the limitations of classical mechanics in explaining microscopic phenomena and then constructing a new theory with new postulates, like superposition, that can successfully describe these phenomena.  This is not a derivation in the mathematical sense of manipulating equations, but rather a paradigm shift in how we describe physical reality.

In summary, while we cannot provide a step-by-step mathematical derivation of superposition from classical mechanics, we can highlight the experimental and theoretical necessity for moving from a classical view of definite properties to a quantum view incorporating superposition to accurately describe the behavior of particles at the quantum level. Quantum mechanics, with its principle of superposition, is a more fundamental and comprehensive theory that encompasses classical mechanics as a limiting case for macroscopic systems where quantum effects become negligible.

\end{document}

thoughts

The user wants me to modify a LaTeX file.
The modifications are:

  1. Add labels to each equation. The labels should be descriptive, contain no spaces, and be unique.
  2. Add references to equations in the text. Replace phrases like "substitute the forces" with "substitute Eq.~\ref{}" and fill in the correct label.

Let's go through the LaTeX file and identify each equation.
For each equation, I will create a descriptive label without spaces.
Then, I will read through the text and find places where an equation might be implicitly referenced, and explicitly reference it using Eq.~\ref{}.

Equation 1: Hamiltonian in classical mechanics: H(x, p) = \frac{p^2}{2m} + V(x)
Label: Classical_Hamiltonian

Equation 2: Hamilton's equation for $\dot{x}$: \dot{x} = \frac{\partial H}{\partial p}
Label: Hamiltons_x_dot_general

Equation 3: Hamilton's equation for $\dot{x}$ in terms of p and m: \dot{x} = \frac{p}{m}
Label: Hamiltons_x_dot_specific

Equation 4: Hamilton's equation for $\dot{p}$: \dot{p} = -\frac{\partial H}{\partial x}
Label: Hamiltons_p_dot_general

Equation 5: Hamilton's equation for $\dot{p}$ in terms of V(x): \dot{p} = -\frac{dV(x)}{dx}
Label: Hamiltons_p_dot_potential

Equation 6: Hamilton's equation for $\dot{p}$ in terms of F(x): \dot{p} = F(x)
Label: Hamiltons_p_dot_force

Equation 7: Definition of $\dot{x}$: \dot{x} = \frac{dx}{dt}
Label: x_dot_definition

Equation 8: Definition of $\dot{p}$: \dot{p} = \frac{dp}{dt}
Label: p_dot_definition

Equation 9: Definition of F(x): F(x) = -\frac{dV(x)}{dx}
Label: Force_from_potential

Equation 10: Quantum superposition equation: |\psi \rangle = c_1 |\uparrow \rangle + c_2 |\downarrow \rangle
Label: Quantum_Superposition

Equation 11: Normalization condition for probabilities: |c_1|^2 + |c_2|^2 = 1
Label: Normalization_Condition

Now, let's go through the text and add the references.
"The Hamiltonian $H$ is given by:" -> "The Hamiltonian $H$ is given by Eq.\ref{Classical_Hamiltonian}:"
"The time evolution of position and momentum is then given by Hamilton's equations:" -> "The time evolution of position and momentum is then given by Hamilton's equations, Eq.
\ref{Hamiltons_x_dot_general} and Eq.\ref{Hamiltons_p_dot_general}:"
"$\dot{x} = \frac{p}{m}$" -> "which simplifies to Eq.
\ref{Hamiltons_x_dot_specific}" (referring to the previous equation being a general form)
"$\dot{p} = -\frac{dV(x)}{dx}$" -> "which simplifies to Eq.\ref{Hamiltons_p_dot_potential}" (referring to the previous equation being a general form)
"$\dot{p} = F(x)$" -> "which is also expressed as Eq.
\ref{Hamiltons_p_dot_force}" (referring to previous equation being another form)
"where:" followed by definition of $\dot{x}$ -> "where Eq.\ref{x_dot_definition} defines $\dot{x}$"
"$\dot{p} = \frac{dp}{dt}$" -> "and Eq.
\ref{p_dot_definition} defines $\dot{p}$"
" $F(x) = -\frac{dV(x)}{dx}$" -> "and Eq.\ref{Force_from_potential} defines $F(x)$"
"A general spin state $|\psi \rangle$ can be a linear combination of these basis states:" -> "A general spin state $|\psi \rangle$ can be a linear combination of these basis states, as shown in Eq.
\ref{Quantum_Superposition}:"
"For a normalized state, we must have:" -> "For a normalized state, as described by Eq.~\ref{Normalization_Condition}, we must have:"

Let's double check the labels for uniqueness and descriptiveness. All labels seem unique and descriptive.
Let's put it all together in the LaTeX file.

response

\documentclass{article}
\usepackage{amsmath}

\title{Bridging Classical and Quantum Views: Superposition}
\author{Ben Payne}
\date{\today}

% margins of 1 inch:
\setlength{\topmargin}{-.5in}
\setlength{\textheight}{9in}
\setlength{\oddsidemargin}{0in}
\setlength{\textwidth}{6.5in}

\usepackage[pdftex]{hyperref} % hyperlink equation and bibliographic citations


\begin{document}
\maketitle

\section{Classical View of Particles}

In classical mechanics, a particle is described by its definite properties at any given time. These properties include, but are not limited to, position, momentum, and spin.  The state of a classical particle can be fully specified by these properties.

Let's consider a particle's position and momentum in one dimension. In classical mechanics, at any time $t$, a particle has a definite position $x(t)$ and a definite momentum $p(t)$. The state of the particle is represented by a point in phase space $(x, p)$.

The classical state of a particle is definite and evolves deterministically according to classical equations of motion, such as Newton's laws or Hamiltonian equations. For instance, under a potential force $V(x)$, the Hamiltonian $H$ is given by Eq.~\ref{Classical_Hamiltonian}:
\begin{equation}
H(x, p) = \frac{p^2}{2m} + V(x)
\label{Classical_Hamiltonian}
\end{equation}
where:
\begin{itemize}
    \item $H$ is the Hamiltonian of the system.
    \item $x$ is the position of the particle.
    \item $p$ is the momentum of the particle.
    \item $m$ is the mass of the particle.
    \item $V(x)$ is the potential energy as a function of position.
\end{itemize}

The time evolution of position and momentum is then given by Hamilton's equations, Eq.~\ref{Hamiltons_x_dot_general} and Eq.~\ref{Hamiltons_p_dot_general}:

\begin{equation}
\dot{x} = \frac{\partial H}{\partial p}
\label{Hamiltons_x_dot_general}
\end{equation}
which simplifies to Eq.~\ref{Hamiltons_x_dot_specific}
\begin{equation}
    \dot{x} = \frac{p}{m}
    \label{Hamiltons_x_dot_specific}
\end{equation}

\begin{equation}
\dot{p} = -\frac{\partial H}{\partial x}
\label{Hamiltons_p_dot_general}
\end{equation}
which simplifies to Eq.~\ref{Hamiltons_p_dot_potential}
\begin{equation}
\dot{p} = -\frac{dV(x)}{dx}
\label{Hamiltons_p_dot_potential}
\end{equation}
which is also expressed as Eq.~\ref{Hamiltons_p_dot_force}
\begin{equation}
\dot{p} = F(x)
\label{Hamiltons_p_dot_force}
\end{equation}
where:
\begin{equation}
\dot{x} = \frac{dx}{dt}
\label{x_dot_definition}
\end{equation}
defines $\dot{x}$ is the time derivative of position (velocity).
\begin{equation}
\dot{p} = \frac{dp}{dt}
\label{p_dot_definition}
\end{equation}
defines $\dot{p}$ is the time derivative of momentum (force).
 \begin{equation}
F(x) = -\frac{dV(x)}{dx}
\label{Force_from_potential}
 \end{equation}
 defines $F(x)$ is the force acting on the particle.


These equations dictate a deterministic evolution of the particle's state. If we know the initial position $x(0)$ and momentum $p(0)$, we can, in principle, determine $x(t)$ and $p(t)$ for all future times $t$.  There is no concept of a particle being in multiple states simultaneously in classical mechanics.

\section{Limitations of Classical Mechanics and the Emergence of Quantum Concepts}

Classical mechanics, while successful in describing macroscopic phenomena, fails to explain many microscopic phenomena observed at the atomic and subatomic levels.  Experiments revealed behaviors that are inconsistent with the classical view of particles having definite properties at all times.

Consider the phenomenon of electron spin.  In classical physics, spin could be thought of as an intrinsic angular momentum vector with a definite direction. However, experiments like the Stern-Gerlach experiment showed that when a beam of silver atoms (with a net spin due to an unpaired electron) passes through an inhomogeneous magnetic field, the beam splits into discrete components, not a continuous spread as would be expected classically. For spin-1/2 particles like electrons, the beam splits into two components, traditionally labeled "spin-up" and "spin-down" along the direction of the magnetic field.

This suggests that the spin component along a particular direction is quantized and can only take on discrete values, unlike a classical continuous vector. Furthermore, if we prepare a beam of spin-up electrons (relative to the z-axis) and then measure their spin along the x-axis, we find that approximately half are measured as spin-up and half as spin-down along the x-axis.  This is not compatible with the classical notion of a definite spin vector that simply has a fixed orientation in space.

To explain these observations, quantum mechanics was developed. A key concept in quantum mechanics is the idea of superposition.

\section{Quantum Mechanical Superposition}

In quantum mechanics, the state of a particle is described by a wave function or a state vector in a Hilbert space. Unlike classical mechanics, physical properties are not always definite until measured. Instead, a quantum system can exist in a superposition of multiple states.

For example, the spin state of an electron can be represented as a vector in a two-dimensional Hilbert space spanned by the basis states $| \uparrow \rangle$ (spin-up) and $| \downarrow \rangle$ (spin-down) along a chosen direction (e.g., z-axis). A general spin state $|\psi \rangle$ can be a linear combination of these basis states, as shown in Eq.~\ref{Quantum_Superposition}:
\begin{equation}
|\psi \rangle = c_1 |\uparrow \rangle + c_2 |\downarrow \rangle
\label{Quantum_Superposition}
\end{equation}
where:
\begin{itemize}
    \item $|\psi \rangle$ is the quantum state vector representing the spin state of the electron.
    \item $|\uparrow \rangle$ represents the spin-up state along the chosen direction (e.g., z-axis).
    \item $|\downarrow \rangle$ represents the spin-down state along the chosen direction (e.g., z-axis).
    \item $c_1$ and $c_2$ are complex coefficients.
\end{itemize}

The coefficients $c_1$ and $c_2$ are complex numbers, and their squared magnitudes, $|c_1|^2$ and $|c_2|^2$, represent the probabilities of finding the electron in the spin-up state and spin-down state, respectively, when a measurement of spin along the chosen direction is performed.  For a normalized state, as described by Eq.~\ref{Normalization_Condition}, we must have:

\begin{equation}
|c_1|^2 + |c_2|^2 = 1
\label{Normalization_Condition}
\end{equation}

This superposition principle is a fundamental postulate of quantum mechanics and does not have a direct analog in classical mechanics.  It implies that before a measurement, the electron's spin state is not definitely "up" or "down," but rather exists in a combination of both possibilities.  The act of measurement forces the system to "choose" one of the definite states, with probabilities given by the squared magnitudes of the coefficients in the superposition.

\section{Bridging the Gap: No Direct Derivation, but a Shift in Description}

It is important to understand that there is no direct mathematical derivation that starts from classical mechanics and naturally leads to the concept of quantum superposition. Quantum mechanics is not a derivation or a refinement of classical mechanics; it is a fundamentally different theory that describes nature at a deeper level.

The transition from classical mechanics to quantum mechanics was driven by experimental observations that classical physics could not explain. The concept of superposition was introduced as part of a new theoretical framework that could account for these observations.  It is a postulate of quantum mechanics, supported by vast experimental evidence, rather than a derived result from classical principles.

One can argue that the "derivation" is historical and conceptual.  It is a process of recognizing the limitations of classical mechanics in explaining microscopic phenomena and then constructing a new theory with new postulates, like superposition, that can successfully describe these phenomena.  This is not a derivation in the mathematical sense of manipulating equations, but rather a paradigm shift in how we describe physical reality.

In summary, while we cannot provide a step-by-step mathematical derivation of superposition from classical mechanics, we can highlight the experimental and theoretical necessity for moving from a classical view of definite properties to a quantum view incorporating superposition to accurately describe the behavior of particles at the quantum level. Quantum mechanics, with its principle of superposition, is a more fundamental and comprehensive theory that encompasses classical mechanics as a limiting case for macroscopic systems where quantum effects become negligible.

\end{document}

@bhpayne bhpayne changed the title derivation: classical particles and quantum superposition bridge derivation: classical particles and quantum superposition Jan 29, 2025
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